I don't know if you can but I know that if you put chimchar, monferno, or infernape in the daycare with a ditto an egg will appear and it should be chimchar
You can but you have to go to stark mountain and saerch it took me a few days.
You can't cacth it.. Just start with it in the begining of the game. .
You can Trade , I think do it with action Replay ds , Do it as begginer pokemon or get a ditto and get a chimchar or monferno ar Infernape to make a chimchar egg.
Just start the game with getting chimchar from Rowan
Get it as your starter
I get a chimchar
This is not possible without a cheat. I can't say any more because there is no more. Trade or cheat are your two option's.
You can gte a egg for it thats what I got a egg from the day-care couple
Get a action replay and theres a cheat that lets you catch Trainer pokemon. Battle a Trainer on route 216 I think and steal there chimchar
You can't catch chimchar you get to choose a pokemon at the start chimchar piplug or turtwig
You can put a chimchar with a ditto and they will have an egg. But I know you can catch a turtwig on route... Uh... Where spring path is. In the long grass. I've got all 3 starter pokemon and about 6 of each starter pokemon. :) :P :D