Relation and Relation schema are the terminologies of SQL and Relation is known as Table and Relation Schema is known as Table definition. In other words, Relation schema defines the meta data elements which represent a particular domain. For example, they define the structures and constraints of data. On the other hand, relation is the predicate for example, Relation schema for a person "relation" can be shown in the following manner:
Person(FirstName, LastName, Age, Gender, Address)
Person(FirstName, LastName, Age, Gender, Address)